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Acid-functionalized fullerenes used as interfacial layer materials in inverted polymer solar cells

Identifieur interne : 000329 ( Chine/Analysis ); précédent : 000328; suivant : 000330

Acid-functionalized fullerenes used as interfacial layer materials in inverted polymer solar cells

Auteurs : RBID : Pascal:13-0345488

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English descriptors

Abstract

Two types of carboxylic acid functionalized fullerence derivatives, 4-(2-ethylhexyloxy)-[6,6]-phenyl C61-butyric acid (p-EHO-PCBA) and bis-4-(2-ethylhexyloxy)-[6,6]-phenyl C61-butyric acid (bis-p-EHO-PCBA), were synthesized and investigated as an interfacial layer for inverted polymer solar cells (iPSCs). The -COOH groups on the PCBAs chemisorb to inorganic metal oxide (TiOx), generating fullerene-based self-assembled monolayers (FSAMs). The devices with the mono- and bis-FSAMs exhibited substantially lower series resistance (Rs) values of 2.10 Ω cm2 and 1.46 cm2, compared to that (4.15 Ω cm2) of the unmodified device. The TiOx films modified with mono- and bis-FSAMs showed higher contact angles of 50° and 91°, respectively, than that of the pristine TiOx film (33°). The increased contact angles were attributed to the enhanced hydrophobicity, improving the wetting properties with the organic photoactive layer. In addition, a comparison of device characteristics with electroactive FSAMs and non-electroactive benzoic acid SAMs clearly indicates that the FSAMs may suggest an additional pathway for photo-induced charge transfer and charge collection to ITO. After surface modification with FSAMs, the short-circuit current density (JSC) and fill factor (FF) values increased substantially. The iPSCs based on poly(5,6-bis(octyloxy)-4-(thiophen-2-1)benzo[c][1,2,5]thiadiazole) (PTBT) and [6,6]phenyl-C61-butyric acid methyl ester (PCBM) as an active layer showed remarkably improved power conversion efficiency up to 5.13% through incorporation of the FSAMs-based interfacial layer.

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Pascal:13-0345488

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<term>Active layer</term>
<term>Butyric acid</term>
<term>Charge collection</term>
<term>Charge transfer</term>
<term>Chemical modification</term>
<term>Chemisorption</term>
<term>Comparative study</term>
<term>Contact angle</term>
<term>Conversion rate</term>
<term>Doped materials</term>
<term>Energy conversion</term>
<term>Ester</term>
<term>Fill factor</term>
<term>Fullerene compounds</term>
<term>Fullerenes</term>
<term>Functionalization</term>
<term>Hydrophobicity</term>
<term>Indium oxide</term>
<term>Interfacial layer</term>
<term>Organic solar cells</term>
<term>Photoinduced effect</term>
<term>Self-assembled layer</term>
<term>Series resistance</term>
<term>Short circuit currents</term>
<term>Surface properties</term>
<term>Surface treatment</term>
<term>Tin addition</term>
<term>Titanium oxide</term>
<term>Wetting</term>
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<term>Fonctionnalisation</term>
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<term>Couche interfaciale</term>
<term>Cellule solaire organique</term>
<term>Chimisorption</term>
<term>Résistance série</term>
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<term>Taux conversion</term>
<term>Fullerènes</term>
<term>Acide butyrique</term>
<term>Oxyde de titane</term>
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<term>Oxyde d'indium</term>
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<div type="abstract" xml:lang="en">Two types of carboxylic acid functionalized fullerence derivatives, 4-(2-ethylhexyloxy)-[6,6]-phenyl C
<sub>61</sub>
-butyric acid (p-EHO-PCBA) and bis-4-(2-ethylhexyloxy)-[6,6]-phenyl C
<sub>61</sub>
-butyric acid (bis-p-EHO-PCBA), were synthesized and investigated as an interfacial layer for inverted polymer solar cells (iPSCs). The -COOH groups on the PCBAs chemisorb to inorganic metal oxide (TiO
<sub>x</sub>
), generating fullerene-based self-assembled monolayers (FSAMs). The devices with the mono- and bis-FSAMs exhibited substantially lower series resistance (R
<sub>s</sub>
) values of 2.10 Ω cm
<sup>2</sup>
and 1.46 cm
<sup>2</sup>
, compared to that (4.15 Ω cm
<sup>2</sup>
) of the unmodified device. The TiO
<sub>x</sub>
films modified with mono- and bis-FSAMs showed higher contact angles of 50° and 91°, respectively, than that of the pristine TiO
<sub>x</sub>
film (33°). The increased contact angles were attributed to the enhanced hydrophobicity, improving the wetting properties with the organic photoactive layer. In addition, a comparison of device characteristics with electroactive FSAMs and non-electroactive benzoic acid SAMs clearly indicates that the FSAMs may suggest an additional pathway for photo-induced charge transfer and charge collection to ITO. After surface modification with FSAMs, the short-circuit current density (J
<sub>SC</sub>
) and fill factor (FF) values increased substantially. The iPSCs based on poly(5,6-bis(octyloxy)-4-(thiophen-2-1)benzo[c][1,2,5]thiadiazole) (PTBT) and [6,6]phenyl-C
<sub>61</sub>
-butyric acid methyl ester (PCBM) as an active layer showed remarkably improved power conversion efficiency up to 5.13% through incorporation of the FSAMs-based interfacial layer.</div>
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<sub>61</sub>
-butyric acid (bis-p-EHO-PCBA), were synthesized and investigated as an interfacial layer for inverted polymer solar cells (iPSCs). The -COOH groups on the PCBAs chemisorb to inorganic metal oxide (TiO
<sub>x</sub>
), generating fullerene-based self-assembled monolayers (FSAMs). The devices with the mono- and bis-FSAMs exhibited substantially lower series resistance (R
<sub>s</sub>
) values of 2.10 Ω cm
<sup>2</sup>
and 1.46 cm
<sup>2</sup>
, compared to that (4.15 Ω cm
<sup>2</sup>
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films modified with mono- and bis-FSAMs showed higher contact angles of 50° and 91°, respectively, than that of the pristine TiO
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<sub>SC</sub>
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</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Photoinduced effect</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Efecto fotoinducido</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Transfert charge</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Charge transfer</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Transferencia carga</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Collection charge</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Charge collection</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Addition étain</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Tin addition</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="GER">
<s0>Zinnzusatz</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Adición estaño</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Traitement surface</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Surface treatment</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="GER">
<s0>Oberflaechenbehandlung</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Tratamiento superficie</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Propriété surface</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Surface properties</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="GER">
<s0>Oberflaecheneigenschaft</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Propiedad superficie</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Courant court circuit</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG">
<s0>Short circuit currents</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Facteur remplissage</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Fill factor</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Couche active</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Active layer</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Capa activa</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Conversion énergie</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Energy conversion</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Conversión energética</s0>
<s5>20</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Taux conversion</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Conversion rate</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Factor conversión</s0>
<s5>21</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Fullerènes</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Fullerenes</s0>
<s5>22</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>Acide butyrique</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Butyric acid</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Butírico ácido</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>Oxyde de titane</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG">
<s0>Titanium oxide</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="GER">
<s0>Titanoxid</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA">
<s0>Titanio óxido</s0>
<s5>24</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Couche autoassemblée</s0>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Self-assembled layer</s0>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Capa autoensamblada</s0>
<s5>25</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Oxyde d'indium</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="GER">
<s0>Indiumoxid</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>26</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE">
<s0>Ester</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="ENG">
<s0>Ester</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="GER">
<s0>Ester</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA">
<s0>Ester</s0>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="3" l="FRE">
<s0>Composé du fullerène</s0>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="3" l="ENG">
<s0>Fullerene compounds</s0>
<s5>28</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE">
<s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="29" i2="3" l="ENG">
<s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE">
<s0>8105T</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>8116D</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fN21>
<s1>329</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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